Deliquescing salts taking up moisture from the Mars atmosphere: Difference between revisions
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As the salt / liquid solution cools in Mars simulation conditions, then the results can be complicated, because for instance MgSO4 releases heat in an exothermic reaction when it crystallizes. This keeps it liquid for longer than you'd expect. In their experiments, it remained liquid for twelve hours as it gradually cooled below the eutectic temperature before eventually it froze at 15.5 degrees below the eutectic temperature. In simulated Mars conditions you also have to take account of the effect of soil mixed in with the salts. Surprisingly, using Mars analogue soil, this does not reduce the supercooling and can in some cases permit more supercooling.<ref name="TonerCatling2014">{{cite journal|url=http://faculty.washington.edu/dcatling/Toner2014_SupercoolSalts.pdf|last1=Toner|first1=J.D.|last2=Catling|first2=D.C.|last3=Light|first3=B.|title=The formation of supercooled brines, viscous liquids, and low-temperature perchlorate glasses in aqueous solutions relevant to Mars|journal=Icarus|volume=233|year=2014|pages=36–47|issn=0019-1035|doi=10.1016/j.icarus.2014.01.018|bibcode=2014Icar..233...36T}}</ref><ref name="GoughChevrier2014">{{cite journal|url=http://comp.uark.edu/~vchevrie/sub/papers/Gough%20-%202014%20-%20EPSL%20-%20perchlorate%20chloride%20mixture%20deliquescence.pdf|last1=Gough|first1=R.V.|last2=Chevrier|first2=V.F.|last3=Tolbert|first3=M.A.|title=Formation of aqueous solutions on Mars via deliquescence of chloride–perchlorate binary mixtures|journal=Earth and Planetary Science Letters|volume=393|year=2014|pages=73–82|issn=0012-821X|doi=10.1016/j.epsl.2014.02.002|bibcode=2014E&PSL.393...73G}}</ref> |
As the salt / liquid solution cools in Mars simulation conditions, then the results can be complicated, because for instance MgSO4 releases heat in an exothermic reaction when it crystallizes. This keeps it liquid for longer than you'd expect. In their experiments, it remained liquid for twelve hours as it gradually cooled below the eutectic temperature before eventually it froze at 15.5 degrees below the eutectic temperature. In simulated Mars conditions you also have to take account of the effect of soil mixed in with the salts. Surprisingly, using Mars analogue soil, this does not reduce the supercooling and can in some cases permit more supercooling.<ref name="TonerCatling2014">{{cite journal|url=http://faculty.washington.edu/dcatling/Toner2014_SupercoolSalts.pdf|last1=Toner|first1=J.D.|last2=Catling|first2=D.C.|last3=Light|first3=B.|title=The formation of supercooled brines, viscous liquids, and low-temperature perchlorate glasses in aqueous solutions relevant to Mars|journal=Icarus|volume=233|year=2014|pages=36–47|issn=0019-1035|doi=10.1016/j.icarus.2014.01.018|bibcode=2014Icar..233...36T}}</ref><ref name="GoughChevrier2014">{{cite journal|url=http://comp.uark.edu/~vchevrie/sub/papers/Gough%20-%202014%20-%20EPSL%20-%20perchlorate%20chloride%20mixture%20deliquescence.pdf|last1=Gough|first1=R.V.|last2=Chevrier|first2=V.F.|last3=Tolbert|first3=M.A.|title=Formation of aqueous solutions on Mars via deliquescence of chloride–perchlorate binary mixtures|journal=Earth and Planetary Science Letters|volume=393|year=2014|pages=73–82|issn=0012-821X|doi=10.1016/j.epsl.2014.02.002|bibcode=2014E&PSL.393...73G}}</ref> |
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With some of the salt solutions, depending on chemical composition, then the supercooling produces a glassy state instead of crystallization, and this could help to protect supercooled microbes from damage. |
With some of the salt solutions, depending on chemical composition, especially magnesium and calcium perchlorates, then the supercooling produces a glassy state instead of crystallization, and this could help to protect supercooled microbes from damage<ref name="TonerCatling2014"/>. Toner et al also found that the magnesium and calcium perchlorate supercooled solutions are so stable that they should keep the brines liquid througout the day night cycle and it is possible they could remain supercooled from summer through to winter and then through to the next summer<ref name="TonerCatling2014"/> |
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===Effects of micropores in salt pillars=== |
===Effects of micropores in salt pillars=== |
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